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This could be the result of a couple things. Components such as coolant temperature sensors or even the fuel pump can cause a hard or no start condition.
First, here is a link that explains what to look for when you have a crank/no start condition:
https://www.2carpros.com/articles/car-cranks-but-wont-start
Now, since it will start with starting fluid, that tells me it is a fuel related issue and not ignition. So, the next thing to do is check fuel pressure. This should be done when the vehicle has sat long enough to cause the problem. Here is a link that shows how in general pressure is tested. What I need you to pay attention to is fuel pressure drop off. Basically, when the key is turned off, you need to see how long pressure maintains before it slowly drops.
https://www.2carpros.com/articles/how-to-check-fuel-system-pressure-and-regulator
Here are the directions specific to your vehicle for testing fuel pressure. The attached picture correlates with the directions. Also, pressure specifications are included in the directions.
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FUEL SYSTEM - PRESSURE TEST - KV6 - NAS
Fuel System - Pressure Test - KV6 - NAS
Service Repair No - 19.50.13
Remove
1. Remove acoustic cover.
2. Position absorbent cloth beneath fuel rail.
WARNING: Fuel vapor is highly flammable and in confined spaces is also explosive and toxic. Always have a fire extinguisher containing foam, CO2, gas or powder close at hand when handling or draining fuel.
3. Up to 03MY: Remove nut and bolt securing coil and position coil aside.
pic 1
4. Connect adaptor LRT-19-006, to pressure gauge LRT-19-004.
5. Remove schraeder valve cap.
6. Connect pressure gauge to fuel rail schraeder valve.
7. Start engine. Pressure at idle = 3.4 bar. If pressure is below 3.4 bar, suspect the following in order: fuel hoses, filter, regulator and pump.
Refit
1. Stop engine.
2. Disconnect pressure gauge LRT-19-006 and adapter LRT-19-004 from fuel rail.
3. Up to 03MY: Fit and tighten nut and bolt securing coil.
4. Fit acoustic cover.
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Start with this and let me know the results. Also, please feel free to ask questions or to let me know if you need help.
Take care,
Joe
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Monday, June 10th, 2019 AT 8:59 PM