There's a couple points of confusion. You are correct that 14 volts indicates the alternator is working, (we want to see between 13.75 and 14.75 volts), but even a defective alternator with one of it's six diodes failed can maintain 14.0 volts. If it helps to make sense of this, consider the 50 psi of water pressure in your garden hose when the nozzle is closed. That's fine pressure, but if there's a kink in the hose, you won't be able to put out a small camp fire when the nozzle is opened. Similarly, full flow from a garden hose won't put out a forest fire. For that you need 50 psi from a fire hydrant and hose.
The point is there's voltage, (electrical pressure) and current, (electrical volume, or flow). The smallest alternator available for my '80 Volare was 45 amps. For today's cars, it's common to find alternators capable of developing well over 150 amps. Both of them are still regulated at between 13.75 and 14.75 volts. Also, both of them develop very little current at idle or low speeds. The alternator in my Volare could easily keep up at idle and recharge the battery because the only electrical item was the ignition module. Your car has dozens of computers, an electric fuel pump, fuel injectors, and electric radiator fans. It could take a good 30 - 50 amps to keep those things running. Chances are the alternator won't be able to develop that much current at idle, so the battery will have to make up the difference as it slowly runs down. This happens to most models when you're idling at a red light, but the majority of drive time is at higher engine speeds that give the battery time to charge back up.
This article:
https://www.2carpros.com/articles/how-to-check-a-car-alternator
explains how to test the charging system. You've already done the first step, but correct charging system voltage only means it's okay to continue with the rest of the tests. A professional load tester is needed for that. The article describes putting the charging system under a load to see if the alternator can meet the demands of the system, and that is sufficient for your needs. With the professional test, the mechanic will dial in the alternator's maximum rated capacity, then test to see if it can develop that much current. The test for "ripple" voltage is automatic, but most testers only show it on a relative bar graph, not as an actual voltage. If the alternator has one failed diode, ripple voltage will be very high, and the maximum the alternator will be able to develop is exactly one third of its rated capacity. At this point, unless testing proves otherwise, I have a suspicion there's nothing wrong with the charging system.
If I understand correctly in your original post, the engine stalled while you weren't there to observe any other clues, so we don't know for sure what led up to that. From your last reply, some additional things come to mind. The first is a failing crankshaft position sensor or camshaft position sensor. Both commonly fail on all car models by becoming heat-sensitive. They continue working as long as the car is moving. Natural air flow keeps them cool. It's when you stop for a short time, such as to get gas, that engine heat has a chance to migrate up to those sensors, causing one to fail resulting in a crank / no-start condition. They commonly work again after cooling down for about an hour. To add to the frustration, a diagnostic fault code often doesn't set at this time to tell us where to start looking. The computer needs more time, as in when a stalling engine is coasting to a stop while you're driving, to detect the missing signal. For that reason we can never rule out one of those sensors just because no code is set related to them. With extended idling, there's again the chance for engine heat to reach those sensors. The clue here is even with a jump-start, the engine will crank but not run for up to an hour, then it will run normally.
My other thought has to do with a loose or corroded connection where the smaller battery positive wire bolts to the under-hood fuse box. This is also common today on all car models. It causes everything to be dead, like you described, and often a jump-start gets the engine started. It's actually the wiggling of the battery cables that does it as the jumper cables are clamped on. The clue is everything is totally dead, as if there was no battery in the car. With a battery that's just badly discharged, there's usually a little observable activity on the dash. You might want to check that nut at the fuse box to be sure it's tight. I check them on every oil change.
As for the rattling noise, worn timing chains can do that, but your engine uses a belt. Water pumps on this engine usually don't make noise until they're bad enough to leak. Also, at the mileage you listed, it's much too early to expect a water pump failure unless the coolant wasn't replaced on a regular basis. The corrosion inhibitors and water pump lubricant additives wear out in about two years, then the coolant becomes acidic leading to corroded parts. If there's no leakage yet, the best approach is to listen near the front of the engine with a stethoscope to try to pinpoint the location of the noise. This drawing shows the water pump is right in the middle of the front of the engine.
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Sunday, June 19th, 2022 AT 7:09 PM