Hi and thanks for using 2CarPros.com. The air escaping when you open the cap is normal. The system builds pressure and it is released when you open it.
As far as the thermostat, that is my first suspect. However, start with this first if you are losing coolant:
https://www.2carpros.com/articles/radiator-pressure-test
Here are directions related to checking the thermostat:
https://www.2carpros.com/articles/how-an-engine-thermostat-works
General directions for replacing the thermostat:
https://www.2carpros.com/articles/replace-thermostat
Here are directions which are specific to the 3.4L V6. I am not sure which V6 you have. The first attached picture correlates with these directions.
Engine Coolant Thermostat Replacement (RPO LNJ) (3.4L)
Removal Procedure
Remove the fuel injector sight shield. Refer to Fuel Injector Sight Shield Replacement (See: Powertrain ManagementFuel Delivery and Air InductionFuel InjectorService and Repair) .
Drain the coolant until the coolant level is below the thermostat. Refer to Cooling System Draining and Filling (LNJ Static Fill) (See: Service and Repair)Cooling System Draining and Filling (LNJ GE 47716 Fill) (See: Service and Repair)Cooling System Draining and Filling (LY7 Static Fill) (See: Service and Repair)Cooling System Draining and Filling (LY7 GE 47716 Fill) (See: Service and Repair) .
Remove the crossover exhaust pipe. Refer to Exhaust Crossover Pipe Replacement (LNJ) (See: Exhaust SystemExhaust PipeService and Repair) .
Remove the radiator hose from the thermostat housing. Refer to Radiator Inlet Hose Replacement (LNJ Chevrolet) (See: Radiator HoseService and Repair)Radiator Inlet Hose Replacement (LNJ Pontiac) (See: Radiator HoseService and Repair)Radiator Inlet Hose Replacement (LY7).
Remove the thermostat housing bolts (3) and clean any sealer from the bolt threads.
Remove the thermostat housing (1).
Remove the thermostat (2).
Clean the mating surfaces.
Installation Procedure
Install the thermostat (2).
Install the thermostat housing (1).
Install RTV sealer, GM P/N 12378478 (Canadian P/N 88900041) or the equivalent, to the thermostat housing bolt threads.
Notice: Refer to Fastener Notice .
Install the thermostat housing bolts (3).
Tighten the bolts to 25 N.m (18 lb ft).
Install the radiator hose to the thermostat housing. Refer to Radiator Inlet Hose Replacement (LNJ Chevrolet) (See: Radiator HoseService and Repair)Radiator Inlet Hose Replacement (LNJ Pontiac) (See: Radiator HoseService and Repair)Radiator Inlet Hose Replacement (LY7).
Install the crossover exhaust pipe. Refer to Exhaust Crossover Pipe Replacement (LNJ) (See: Exhaust SystemExhaust PipeService and Repair) .
Install the fuel injector sight shield. Refer to Fuel Injector Sight Shield Replacement (See: Powertrain ManagementFuel Delivery and Air InductionFuel InjectorService and Repair) .
Fill the cooling system. Refer to Cooling System Draining and Filling (LNJ Static Fill) (See: Service and Repair)Cooling System Draining and Filling (LNJ GE 47716 Fill) (See: Service and Repair)Cooling System Draining and Filling (LY7 Static Fill) (See: Service and Repair)Cooling System Draining and Filling (LY7 GE 47716 Fill) (See: Service and Repair) .
Inspect the cooling system for leaks. Repair as necessary.
If you have the 3.6L V6, here are directions specific to it. Picture 2 correlates to these directions.
CONVERSION CALCULATOR
2008 Pontiac Truck Torrent AWD V6-3.6L
Vehicle  Engine, Cooling and Exhaust  Cooling System  Thermostat  Service and Repair
SERVICE AND REPAIR
Engine Coolant Thermostat Replacement (RPO LY7) (3.6L)
Removal Procedure
Partially drain the cooling system. Refer to Cooling System Draining and Filling (LNJ Static Fill) (See: Service and Repair)Cooling System Draining and Filling (LNJ GE 47716 Fill) (See: Service and Repair)Cooling System Draining and Filling (LY7 Static Fill) (See: Service and Repair)Cooling System Draining and Filling (LY7 GE 47716 Fill) (See: Service and Repair) .
Remove the heater inlet and outlet pipes. Refer to Heater Inlet Pipe Replacement (RPO LNJ) (See: Coolant Line/HoseService and Repair)Heater Inlet Pipe Replacement (RPO LY7) (See: Coolant Line/HoseService and Repair) and Heater Outlet Pipe Replacement (RPO LNJ) (See: Coolant Line/HoseService and Repair)Heater Outlet Pipe Replacement (RPO LY7) (See: Coolant Line/HoseService and Repair) .
Remove the thermostat housing bolts (1).
Remove the housing.
Remove the thermostat (3) and discard the thermostat seal (4).
Installation Procedure
Install the thermostat (3) with a NEW thermostat seal (4).
Notice: Refer to Fastener Notice .
Install the thermostat housing bolts (1).
Tighten the thermostat housing bolts to 10 N.m (89 lb in).
Install the heater inlet and outlet pipes. Refer to Heater Inlet Pipe Replacement (RPO LNJ) (See: Coolant Line/HoseService and Repair)Heater Inlet Pipe Replacement (RPO LY7) (See: Coolant Line/HoseService and Repair) and Heater Outlet Pipe Replacement (RPO LNJ) (See: Coolant Line/HoseService and Repair)Heater Outlet Pipe Replacement (RPO LY7) (See: Coolant Line/HoseService and Repair) .
Fill the cooling system. Refer to Cooling System Draining and Filling (LNJ Static Fill) (See: Service and Repair)Cooling System Draining and Filling (LNJ GE 47716 Fill) (See: Service and Repair)Cooling System Draining and Filling (LY7 Static Fill) (See: Service and Repair)Cooling System Draining and Filling (LY7 GE 47716 Fill)
If you notice the engine does not over heat at highway speeds but rather, only when driving in town, pay attention if the cooling fans are turning on. If they do not, that will allow the engine to heat up when not moving.
Let me know if this helps or if you have other questions.
Take care,
Joe
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Saturday, May 26th, 2018 AT 8:34 PM